A Step Towards Cheap Aluminium Batteries

The energy transition depends on technologies that allow the inexpensive temporary storage of electricity from renewable sources. A promising new candidate is aluminium batteries, which are made from cheap and abundant raw materials.

aluminium batteries
The researchers produced aluminium button cells in the laboratory. The battery case is made of stainless steel coated with titanium nitride on the inside to make it corrosion resistant. (Picture: Empa / ETH Zurich)

Scientists from Maksym Kovalenko’s research group, which is based at both ETH Zurich and in Empa’s Laboratory for Thin Films and Photovoltaics, are researching and developing batteries made from abundant raw materials. The researchers have now identified two new materials that could bring about key advances in the development of aluminium batteries. The first is a corrosion-resistant material for the conductive parts of the battery; the second is a novel material for the battery’s positive pole that can be adapted to a wide range of technical requirements.

Aggressive electrolyte fluid

aluminium batteries
Functional scheme of the aluminium batteries, made by Empa and the ETH Zurich. (Picture: Advanced Materials 2018, edited)

As the electrolyte fluid in aluminium batteries is extremely aggressive and corrodes stainless steel, and even gold and platinum, scientists are searching for corrosion-resistant materials for the conductive parts of these batteries. Kovalenko and his colleagues at the Laboratory for Thin Films and Photovoltaics at Empa have found what they are looking for in titanium nitride, a ceramic material that exhibits sufficiently high conductivity. «This compound is made up of the highly abundant elements titanium and nitrogen, and it’s easy to manufacture,» explains Stephan Buecheler from Empa.

The scientists have successfully made aluminium batteries with conductive parts made of titanium nitride in the laboratory. The material can easily be produced in the form of thin films, also as a coating over other materials such as polymer foils. Kovalenko believes it would also be possible to manufacture the conductors from a conventional metal and coat them with titanium nitride, or even to print conductive titanium nitride tracks on to plastic. «The potential applications of titanium nitride are not limited to aluminium batteries. The material could also be used in other types of batteries; for example, in those based on magnesium or sodium, or in high-voltage lithium-ion batteries,» says Kovalenko.

An alternative to graphite

aluminium batteries
Molecular structure of polypyrene (Picture: Advanced Materials 2018)

The second new material can be used for the positive electrode (pole) of aluminium batteries. Whereas the negative electrode in these batteries is made of aluminium, the positive electrode is usually made of graphite. Now, Kovalenko and his team have found a new material that rivals graphite in terms of the amount of energy a battery is able to store. The material in question is polypyrene, a hydrocarbon with a chain-like (polymeric) molecular structure. In experiments, samples of the material – particularly those in which the molecular chains congregate in a disorderly manner – proved to be ideal. «A lot of space remains between the molecular chains. This allows the relatively large ions of the electrolyte fluid to penetrate and charge the electrode material easily,» Kovalenko explains.

One of the advantages of electrodes containing polypyrene is that scientists are able to influence their properties, such as the porosity. The material can therefore be adapted perfectly to the specific application. «In contrast, the graphite used at present is a mineral. From a chemical engineering perspective, it cannot be modified,» says Kovalenko.

As both titanium nitride and polypyrene are flexible materials, the researchers believe they are suitable for use in «pouch cells» (batteries enclosed in a flexible film).

Source : Empa