For decades, solar technology and applications have been dependent on dye-sensitised solar cells (DSSCs). To mimic nature’s absorption of light during photosynthesis, DSSCs use a photoactive dye that absorbs photons and uses their energy to excite electrons, which are then transferred into a nanocrystalline titanium dioxide layer. Although this process works well, the high-temperature processing required for titanium is not compatible with low-cost fabrication methods – an impediment to the mass market production of solar panels and thus a roadblock to increased use of solar energy.
NANOMATCELL researchers took aim at the use of titanium, with the intention of replacing it with innovative new materials and technologies for high-efficiency, solution processed solar cells. Bringing together experts from the fields of material science, chemistry, surface passivation and physics, the team set out to better harness the solar spectrum by inventing both new materials capable of yielding high-power conversion efficiency solar cells and novel panchromatic semiconductors based on environmentally friendly compounds and processes.
Achieving these objectives was no small feat as they required the development of a number of new strategies and components. For example, the team first had to develop new strategies for the synthesis, growth and doping of semiconductor nanocrystals and nanowires. As dye plays a central role in the function of DSSCs, researchers also had to create new dyes capable of taking full advantage of a larger portion of the spectrum – meaning new dyes for short wavelengths and new dyes for enhanced absorption in the near-infrared range had to be created.
Increased market uptake
But that’s just the DSSCs themselves, there was also the challenge of what to do with the light once it was absorbed. Here too researchers made significant developments in improving the overall efficiency of solar cells. In fact, the NANOMATCELL project produced a range of solar cells based on panchromatic inorganic and hybrid absorbers – all of which demonstrate enhanced performance and a potential to reach even further optimisation.
Thanks to the new processing methods developed by the project, ground-breaking efficiencies in excess of 15 % have been reached with some solar cells. In other words, NANOMATCELL advanced the state of DSSCs to such a level of efficiency that widespread market uptake looks likely.
Although the project itself has ended, the impact of its work goes on. According to recently published research in the journal ‘Nature Communications’, a new hybrid photodetector incorporating both graphene and quantum dots is now in the works. The combination of these two material technologies could lead to fast, efficient and low-cost devices capable of detecting across the visible, near-infrared and short-wave (SWIR) spectral regions to a wavelength of around 3 µm.
Researchers believe this novel approach will be compatible with the high-volume silicon CMOS manufacturing process, as well as emerging flexible electronic platforms. As current high-efficiency photo-detection in the SWIR region beyond 1 µm tends to rely on relatively expensive devices, this development represents yet another disruption to the traditional approach to solar cell technology – with many cost-saving benefits to follow.