Graphene and diamonds prove a slippery combination

NST-ES graphene tribology team: Diana Berman (NST), Sanket Deshmukh (NST), Subramanian "Subbu" Sankaranarayanan (NST), Ali Erdemir (ES), Ani Sumant (NST)
NST-ES graphene tribology team: Diana Berman (NST), Sanket Deshmukh (NST), Subramanian "Subbu" Sankaranarayanan (NST), Ali Erdemir (ES), Ani Sumant (NST)
NST-ES graphene tribology team: Diana Berman (NST), Sanket Deshmukh (NST), Subramanian “Subbu” Sankaranarayanan (NST), Ali Erdemir (ES), Ani Sumant (NST)

Scientists at the U.S. Department of Energy’s Argonne National Laboratory have found a way to use tiny diamonds and graphene to give friction the slip, creating a new material combination that demonstrates the rare phenomenon of “superlubricity.”

Led by nanoscientist Ani Sumant of Argonne’s Center for Nanoscale Materials (CNM) and Argonne Distinguished Fellow Ali Erdemir of Argonne’s Energy Systems Division, the five-person Argonne team combined diamond nanoparticles, small patches of graphene – a two-dimensional single-sheet form of pure carbon – and a diamond-like carbon material to create superlubricity, a highly-desirable property in which friction drops to near zero.

According to Erdemir, as the graphene patches and diamond particles rub up against a large diamond-like carbon surface, the graphene rolls itself around the diamond particle, creating something that looks like a ball bearing on the nanoscopic level. “The interaction between the graphene and the diamond-like carbon is essential for creating the ‘superlubricity’ effect,” he said. “The two materials depend on each other.”

At the atomic level, friction occurs when atoms in materials that slide against each other become “locked in state,” which requires additional energy to overcome.  “You can think of it as like trying to slide two egg cartons against each other bottom-to-bottom,” said Diana Berman, a postdoctoral researcher at the CNM and an author of the study. “There are times at which the positioning of the gaps between the eggs – or in our case, the atoms – causes an entanglement between the materials that prevents easy sliding.”

By creating the graphene-encapsulated diamond ball bearings, or “scrolls”, the team found a way to translate the nanoscale superlubricity into a macroscale phenomenon. Because the scrolls change their orientation during the sliding process, enough diamond particles and graphene patches prevent the two surfaces from becoming locked in state.  The team used large-scale atomistic computations  on the Mira supercomputer at the Argonne Leadership Computing Facility to prove that the effect could be seen not merely at the nanoscale but also at the macroscale.

“A scroll can be manipulated and rotated much more easily than a simple sheet of graphene or graphite,” Berman said.

However, the team was puzzled that while superlubricity was maintained in dry conditions, in a humid environment this was not the case. Because this behavior was counterintuitive, the team again turned to atomistic calculations. “We observed that the scroll formation was inhibited in the presence of a water layer, therefore causing higher friction,” explained co-author Argonne computational nanoscientist Subramanian Sankaranarayanan.

While the field of tribology has long been concerned with ways to reduce friction – and thus the energy demands of different mechanical systems – superlubricity has been treated as a tough proposition. “Everyone would dream of being able to achieve superlubricity in a wide range of mechanical systems, but it’s a very difficult goal to achieve,” said Sanket Deshmukh, another CNM postdoctoral researcher on the study.

“The knowledge gained from this study,” Sumant added, “will be crucial in finding ways to reduce friction in everything from engines or turbines to computer hard disks and microelectromechanical systems.”

A paper based on the study, “Macroscale superlubricity enabled by graphene nanoscroll formation,” appeared in the May 14 online issue of Science Express.  The work was funded by the DOE’s Office of Science.  The Center for Nanoscale Materials and the Argonne Leadership Computing Facility are DOE Office of Science User Facilities.

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